Synthesis and Identification of Complexes of [1, 2-diphenyl -2- (pyrazin -2- ylimino)- ethanone oxime] with Some Metal Salts

Authors

  • A.N. Al-Jeboori Chemistry Department.Ibn-AI-Haithem College of Education, University of Baghdad-IRAQ
  • T.H . AL-Noor Chemistry Department.Ibn-AI-Haithem College of Education, University of Baghdad-IRAQ
  • R.L. Sadawi Chemistry Department.Ibn-AI-Haithem College of Education, University of Baghdad-IRAQ

DOI:

https://doi.org/10.32947/ajps.v6i1.366

Abstract

Aim of this work is synthesis and characterization of bidentate Oxime ligand (HL) [1,2-diphenyl-2-(pyrazin-2-ylimino)-ethanoneoxime]. This ligand was prepared by reacting of 2-aminopyrmidine (A) with benzylmonooxime (B) under reflux in methanol and drops of CH3COOH gave the ligand (HL).fig(1) .The prepared ligand were characterized by I.R, U.V-vis spectra and melting point.The ligand were reacted with some metal ions under reflux in methanol with (1:1) ratio gave complexes of the general formula: [M (HL)], Where: M= MnII, FeII, CoII, CuII, ZnII, CdII, NiII, and HgII. These complexes were characterized by (A.A), chloride content I.R, U.V-vis spectra, molar conductivity and melting point. The molar conductance showed that, all complexe are non-electrolyte.

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Published

2009-06-01

How to Cite

Al-Jeboori, A., AL-Noor, T. ., & Sadawi, R. (2009). Synthesis and Identification of Complexes of [1, 2-diphenyl -2- (pyrazin -2- ylimino)- ethanone oxime] with Some Metal Salts. Al Mustansiriyah Journal of Pharmaceutical Sciences, 6(1), 123–134. https://doi.org/10.32947/ajps.v6i1.366